Scientists make first high-resolution 3D images of a polymer solar cell’s insides

Washington, September 14 (ANI): Researchers from the Eindhoven University of Technology and the University of Ulm in Germany have made the first high-resolution 3D images of the inside of a polymer solar cell.

This gives them important new insights in the nanoscale structure of polymer solar cells and its effect on the performance.

The investigations shed new light on the operational principles of polymer solar cells.

These solar cells do not have the high efficiencies of their silicon counterparts yet. Polymer cells, however, can be printed in roll-to-roll processes, at very high speeds, which makes the technology potentially very cost-effective.

Added to that, polymer cells are flexible and lightweight, and therefore suitable to be used on vehicles or clothing or to be incorporated in the design of objects.

In these hybrid solar cells, a mixture of two different materials, a polymer and a metal oxide are used to create charges at their interface when the mixture is illuminated by the sun.

The degree of mixing of the two materials is essential for its efficiency.

Intimate mixing enhances the area of the interface where charges are formed but at the same time obstructs charge transport because it leads to long and winding roads for the charges to travel.

Larger domains do exactly the opposite.

The vastly different chemical nature of polymers and metal oxides generally makes it very difficult to control the nanoscale structure.

The Eindhoven researchers have been able to largely circumvent this problem by using a precursor compound that mixes with the polymer and is only converted into the metal oxide after it is incorporated in the photoactive layer.

This allows better mixing and enables extracting up to 50 percent of the absorbed photons as charges in an external circuit.

The importance of the degree of mixing was clearly demonstrated by visualization of the structure of these blends in three dimensions.

Traditionally such visualization has been extremely challenging, but by using 3D electron tomography, the team has been able to resolve the mixing with unprecedented detail on a nanoscale.

From these images, the researchers at the Institute of Stochastics in Ulm have been able to extract typical distances between the two components, relating to the efficiency of charge generation, and analyze the percolation pathways, that is, how much of each component is connected to the electrode.

These quantitative analyses of the structure matched perfectly with the observed performance of the solar cells in sunlight. (ANI)

Novel light sensor to enhance digital cameras

Washington, June 19 : Performance of a large number of electronic devices, including digital cameras, could soon be enhanced, for researchers have now created light sensor-like a pixel in a digital camera-that benefits from a phenomenon known as multi-exciton generation (MEG).

University of Toronto (UT) scientists, who led the research, claim that they are the first group to have collected an electrical current from a device that makes use of MEG.

“Digital cameras are now universal, but they suffer from a major limitation: they take poor pictures under dim light. One reason for this is that the image sensor chips inside cameras collect, at most, one electron”s worth of current for every photon (particle of light) that strikes the pixel. Instead generating multiple excitons per photon could ultimately lead to better low-light pictures,” said Ted Sargent, professor in UT”s Department of Electrical and Computer Engineering.

In solar cells and digital cameras, particles of light called photons are absorbed in a semiconductor, such a silicon, and generate excited electrons, known as excitons.

Thus, the semiconductor chip measures a current that flows as a result.

Normally, each photon is converted into at most one exciton, which lowers the efficiency of solar cells and it limits the sensitivity of digital cameras.

When a scene is dimly lit, small portable cameras like those in laptops suffer from noise and grainy images as a result of the small number excitons.

“Multi-exciton generation breaks the conventional rules that bind traditional semiconductor devices. This finding shows that it”s more than a fascinating concept: the tangible benefits of multiple excitons can be seen in a light sensor”s measured current,” said Sargent.

Cosmic “ghost” found lurking around supermassive black hole

Washington, May 29 (ANI): NASA’s Chandra X-ray Observatory has found a cosmic “ghost” lurking around a distant supermassive black hole, which is the first detection of such a high-energy apparition, and may be evidence of a huge eruption produced by the black hole.

The X-ray ghost, so-called because a diffuse X-ray source has remained after other radiation from the outburst has died away, is in the Chandra Deep Field-North, one of the deepest X-ray images ever taken.

The source, a.k.a. HDF 130, is over 10 billion light-years away and existed at a time 3 billion years after the Big Bang, when galaxies and black holes were forming at a high rate.

“We’d seen this fuzzy object a few years ago, but didn’t realize until now that we were seeing a ghost”, said Andy Fabian of the Cambridge University in the United Kingdom.

“It’s not out there to haunt us, rather it’s telling us something – in this case what was happening in this galaxy billions of year ago,” he added.

Fabian and colleagues think the X-ray glow from HDF 130 is evidence for a powerful outburst from its central black hole in the form of jets of energetic particles traveling at almost the speed of light.

When the eruption was ongoing, it produced prodigious amounts of radio and X-radiation, but after several million years, the radio signal faded from view as the electrons radiated away their energy.

However, less energetic electrons can still produce X-rays by interacting with the pervasive sea of photons remaining from the Big Bang – the cosmic background radiation.

Collisions between these electrons and the background photons can impart enough energy to the photons to boost them into the X-ray energy band.

This process produces an extended X-ray source that lasts for another 30 million years or so.

“This ghost tells us about the black hole’s eruption long after it has died,” said co-author Scott Chapman, also of Cambridge University. “This means we don’t have to catch the black holes in the act to witness the big impact they have,” he added.

This is the first X-ray ghost ever seen after the demise of radio-bright jets.

In HDF 130, only a point source is detected in radio images, coinciding with the massive elliptical galaxy seen in its optical image.

This radio source indicates the presence of a growing supermassive black hole.

“This result hints that the X-ray sky should be littered with such ghosts, especially if black hole eruptions are as common as we think they are in the early Universe,” said co-author Caitlin Casey, also of Cambridge. (ANI)

“Green bacteria” may be used to build artificial photosynthetic systems

Washington, May 5 (ANI): An international team of scientists has determined the structure of the chlorophyll molecules in green bacteria that are responsible for harvesting light energy, which one day could be used to build artificial photosynthetic systems.

The scientists found that the chlorophylls are highly efficient at harvesting light energy.

“We found that the orientation of the chlorophyll molecules make green bacteria extremely efficient at harvesting light,” said Donald Bryant, Ernest C. Pollard Professor of Biotechnology at Penn State and one of the team’s leaders.

According to Bryant, green bacteria are a group of organisms that generally live in extremely low-light environments, such as in light-deprived regions of hot springs and at depths of 100 meters in the Black Sea.

The bacteria contain structures called chlorosomes, which contain up to 250,000 chlorophylls.

“The ability to capture light energy and rapidly deliver it to where it needs to go is essential to these bacteria, some of which see only a few photons of light per chlorophyll per day,” said Bryant.

Because they have been so difficult to study, the chlorosomes in green bacteria are the last class of light-harvesting complexes to be characterized structurally by scientists.

Scientists typically characterize molecular structures using X-ray crystallography, a technique that determines the arrangement of atoms in a molecule and ultimately gives information that can be used to create a picture of the molecule.

However, X-ray crystallography could not be used to characterize the chlorosomes in green bacteria because the technique only works for molecules that are uniform in size, shape, and structure.

To get around this problem, the team used a combination of techniques to study the chlorosome.

They used genetic techniques to create a mutant bacterium with a more regular internal structure, cryo-electron microscopy to identify the larger distance constraints for the chlorosome, solid-state nuclear magnetic resonance (NMR) spectroscopy to determine the structure of the chlorosome’s component chlorophyll molecules, and modeling to bring together all of the pieces and create a final picture of the chlorosome.

The last steps for the team were to pull together all of their data and to create a detailed computer model of the structure.

“At first, it seems counterintuitive that green bacteria have managed to evolve a better light-harvesting system by increasing disorder in the chlorosome structure,” said Bryant.

Bryant said that the team’s results may one day be used to build artificial photosynthetic systems that convert solar energy to electricity.

“The interactions that lead to the assembly of the chlorophylls in chlorosomes are rather simple, so they are good models for artificial systems,” he said. (ANI)

‘Hidden photons’ may be used to send secret emails through Earth

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London, April 27 (ANI): A team of scientists has proposed the possibility of hypothetical particles called hidden photons being used to send secret emails through the Earth./pp
According to a report in New Scientist, the theory has been put forward by Andreas Ringwald at the German Electron Synchrotron (DESY) in Hamburg, and colleagues./pp
Hidden photons are a class of particles predicted by so-called supersymmetric extensions to the standard model of particle physics. /pp
Unlike normal photons, hidden photons could have a tiny mass and would be invisible because they would not interact with the charged particles in conventional matter. /pp
This means hidden photons would flit through even the densest materials unaffected./pp
The only place to spot them is in a vacuum, where they should sometimes oscillate into normal photons. /pp
There are already experiments searching for this effect: the idea is to shine a laser at a wall in a vacuum and see if any of the photons make it through to the other side by transforming into their hidden counterparts and back again. /pp
According to Ringwald’s group, if these experiments succeed it should be possible to scale up the apparatus so that the hidden photons become signal carriers and the wall becomes any stretch of ground or water./pp
Hypothetical ‘hidden photons’ could beam messages through any stretch of ground or water. /pp
If such particles exist, then we can use them to communicate. It’s very simple, said Ringwald./pp
The benefit of such a communication method is that, unless someone were in the exact line of sight with appropriate equipment, it would be impossible to eavesdrop. /pp
For example, submarines could employ the system to avoid communicating via sound, which is easily intercepted. /pp
Hidden photons could even take messages where radio signals cannot reach, such as the far side of the moon./pp
According to physicist Doug Shaw at Queen Mary, University of London, it would be a technical challenge to line up transmitters and receivers over large distances, but he agrees a system is feasible in principle. /pp
It’s a nice idea, he said. Unlike most hypothetical particles that are only accessible at high energies, these particles, if they exist, would have potentially useful real-world applications, he added. (ANI)/p

Next gen LEDs could shine bright white light for homes and offices

London, April 27 (ANI): The development of a new generation of white organic LEDs (Light-emitting diodes) could become the source of choice for homes, offices and even computer displays.

LEDs are preferable for many applications because they convert electrical energy into photons so efficiently.

While incandescent light bulbs convert only 5 per cent of the energy passing through them into light and compact fluorescent bulbs manage 20 per cent efficiency, LEDs routinely achieve 30 per cent or more.

The problem is that conventional LEDs produce light only at specific wavelengths, so manufacturers have had to employ two tricks to make white light.

One is to use several LEDs that each emit a primary colour. When combined, these colours look white to the human eye.

The other approach is to cover a blue LED in a phosphorescent chemical, or phosphor, that absorbs a portion of the emitted bluish light and re-emits it as amber.
gain, we see the combination as white.

Conventional LEDs produce light only at specific wavelengths. Making white light from them is costly.

These solutions are relatively costly, though.

Now, according to a report in New Scientist, a potentially cheaper option is emerging thanks to the development of organic dyes that emit blue and amber photons, and the ability to combine both in the light-emitting layer of an LED.

The result is an organic LED (WOLED) that produces white light directly.

WOLEDs have not made it out of the lab yet, however.

One problem is that high currents tend to break down the organic dyes they rely on and this dramatically reduces their lifetime compared with inorganic LEDs made of materials such as indium gallium arsenide.

One way around this would be to find a way to achieve an acceptable brightness with as low a current as possible.

Now, a group led by Dongge Ma at the Changchun Institute of Applied Chemistry at the Chinese Academy of Science has come up with a simple way of doing this: stacking two white-light-emitting layers in a single device so that they operate in series.

“The stacked structure allows higher brightness at lower current,” said Paul Burrows, an electronics engineer at Reata Research, a science and technology consultancy in Kennewick, Washington. (ANI)

Higher performance electrical and optical integrated circuits come closer to reality

Washington, March 20 (ANI): Scientists at the University of Illinois have moved a step closer to realising higher speed electronics and higher performance electrical and optical integrated circuits, for they have successfully created a microwave signal mixer made from a tunnel-junction transistor laser.

The researchers have revealed that their mixing device accepts two electrical inputs, and produces an optical signal that was measured at frequencies of up to 22.7 gigahertz.

They say that the frequency range was limited by the bandwidth of the detector employed in the measurements, not by the transistor device.

“In addition to the usual current-modulation capability, the tunnel junction provides an enhanced means for voltage-controlled modulation of the photon output of the transistor laser. This offers new capabilities and a much greater sensitivity for unique signal-mixing and signal-processing applications,” said Nick Holonyak Jr., a John Bardeen Chair Professor of Electrical and Computer Engineering and Physics.

For making the device, the research team placed a quantum well inside the base region of a transistor laser, and then created a tunnel junction within the collector region.

“Within the transistor laser, the tunnelling process occurs predominantly through a process called photon-assisted absorption,” said Milton Feng, the Holonyak Chair Professor of Electrical and Computer Engineering.

According to Feng, the tunnelling process begins in the quantum well, where electrons and holes combine and generate photons, which are then reabsorbed to create new pairs of electrons and holes used for voltage modulation.

“The tunnel junction makes it possible to annihilate an electron in the quantum well, and then tunnel an electron out to the collector by the tunnel contact,” Feng said.

The transistor output is sensitive to third-terminal voltage control because of the electrons tunneling from the base to the collector, which also creates an efficient supply of holes to the quantum well for recombination.

“We are using the photon internally to modify the electrical operation and make the transistor itself a different device with additional properties,” said Holonyak, who also is a professor in the university’s Center for Advanced Study, one of the highest forms of campus recognition.

According to the researchers, high-speed signal mixing is made possible by the nonlinear coupling of the internal optical field to the base electron-hole recombination, minority carrier emitter-to-collector transport, and the base-to-collector electron tunneling at the collector junction.

The sensitivity of the tunnel-junction transistor laser to voltage control enables the device to be directly modulated by both current and voltage.

The researchers say that this flexibility facilitates the design of new non-linear signal processing devices for improved optical power output.

“The metamorphosis of the transistor is not yet complete. We’re still working on it, and the transistor is still changing,” Holonyak said.

The fabrication and operation of the mixing device has been described in the journal Applied Physics Letters. (ANI)

Scientists “squeeze” light to quantum limit

London, Jan 7 (ANI): For the first time, physicists from University of Toronto have developed a new technique to squeeze light to the fundamental quantum limit.

The finding has paved way for potential applications in high-precision measurement, next-generation atomic clocks, novel quantum computing and our most fundamental understanding of the universe.

Krister Shalm, Rob Adamson and Aephraim Steinberg of U of T”s Department of Physics and Centre for Quantum Information and Quantum Control, conducted the study.

“Precise measurement lies at the heart of all experimental science: the more accurately we can measure something the more information we can obtain. In the quantum world, where things get ever-smaller, accuracy of measurement becomes more and more elusive,” Nature quoted PhD graduate student Krister Shalm as saying.

Light is one of the most precise measuring tools in physics, but it has its limits in the world of modern quantum technology. The smallest particle of light is a photon and it is so small that an ordinary light bulb emits billions of photons in a trillionth of a second.

“Despite the unimaginably effervescent nature of these tiny particles, modern quantum technologies rely on single photons to store and manipulate information. But uncertainty, also known as quantum noise, gets in the way of the information,” explained Professor Aephraim Steinberg.

While squeezing is a way to increase certainty in one quantity such as position or speed, it still has a drawback.

“If you squeeze the certainty of one property that is of particular interest, the uncertainty of another complementary property inevitably grows,” he said.

In the current study, the physicists combined three separate photons of light together inside an optical fibre, to create a triphoton.

“A strange feature of quantum physics is that when several identical photons are combined, as they are in optical fibres such as those used to carry the internet to our homes, they undergo an “identity crisis” and one can no longer tell what an individual photon is doing,” said Steinberg.

Then, they squeezed the triphotonic state to glean the quantum information that was encoded in the triphoton´s polarization.

Earlier, the researchers thought that one could squeeze indefinitely, simply tolerating the growth of uncertainty in the uninteresting direction.

“A state of polarization can be thought of as a small continent floating on a sphere. When we squeezed our triphoton continent, at first all proceeded as in earlier experiments. But when we squeezed sufficiently hard, the continent lengthened so much that it began to “wrap around” the surface of the sphere,” said Steinberg.

He added: “To take the metaphor further, all previous experiments were confined to such small areas that the sphere, like your home town, looked as though it was flat. This work needed to map the triphoton on a globe, which we represented on a sphere providing an intuitive and easily applicable visualization. In so doing, we showed for the first time that the spherical nature of polarization creates qualitatively different states and places a limit on how much squeezing is possible.”

“Creating this special combined state allows the limits to squeezing to be properly studied. For the first time, we have demonstrated a technique for generating any desired triphoton state and shown that the spherical nature of polarization states of light has unavoidable consequences. Simply put: to properly visualize quantum states of light, one should draw them on a sphere,” said Rob Adamson.

The findings of the study are in a recent issue of the prestigious international journal Nature. (ANI)